Thianthrene and related heterocycles [Elektronische Ressource] : metal complexes, radical cation salts and semiconductors / vorgelegt von Rachmat Triandi Tjahjanto

Thianthrene and Related Heterocycles:Metal Complexes, Radical Cation Saltsand SemiconductorsD I S S E R T A T I O Nzur Erlangungdes Doktogrades (Dr. rer. nat.)der Mathematisch-Naturwissenschaftlichen Fakultatder Rheinischen Friedrich-Wilhelms-Universitat Bonnvorgelegt vonRachmat Triandi Tjahjanto, M. Sc.ausMakassar/IndonesienBonn 2009Angefertigt mit Genehmigung der Mathematischen-Naturwissenschaftlichen Fakult atder Rheinischen Friedrich-Wilhelms-Universit at Bonn1. Gutachter: Prof. Dr. Johannes Beck2. Gutachter: Prof. Dr. Alexander C. FilippouTag der Promotion: 17.7.2009Erscheinungsjahr: 2009Diese Dissertation ist auf dem Hochschulschriftenserver der ULB Bonn unterhttp://hss.ulb.uni-bonn.de/diss online elektronisch publiziert.AbstractLiquid SO was used as a solvent for complexation as well as redox reactions based2{on thianthrene and related heterocyclic molecules. With silver salt, AgX (X = BF ,4{SbF ), the complexes [Ag (TA) ][BF ] 3 SO (1) and [Ag (TA) ][SbF ] 5 SO (2),6 2 2 4 2 2 2 3 6 2 2and with gold(III) chloride, the complex [AuCl (TA) ][AuCl ] (3) were obtained.2 2 4+The oxidation products contain radical cations of thianthrene, TA , as found in the structure of (TA )(HSO ) H SO (5) and (TA )[FeCl ] (6), radical cation of se-4 2 4 4 lenanthrene in the structure of (SA )[AlCl ] (8) and (SA ) [SO (BF ) ] (10), and4 2 4 3 2a structure with a bridging oxygen of -oxy-selenanthrene(2+), SAO(HSO ) (9).