Synthesis of chiral phosphino-sulfoximines through phospha-Michael addition and their evaluation as 1,5-P,N-ligand in asymmetric allylic alkylation [Elektronische Ressource] / vorgelegt von Fabien Lemasson

Synthesis of Chiral Phosphino-Sulfoximines Through Phospha-Michael Addition and Their Evaluation as 1,5-P,N-Ligand in Asymmetric Allylic Alkylation Von der Fakultät für Mathematik, Informatik und Naturwissenschaften der RWTH Aachen University zur Erlangung des akademischen Grades eines Doktors der Naturwissenschaften genehmigte Dissertation vorgelegt von Master of Science Fabien Lemasson aus Rennes (Frankreich) Berichter: Universitätsprofessor Dr. Ing. Hans-Joachim Gais Universitätsprofessor Dr. rer. nat. Dieter Enders Tag der mündlichen Prüfung: 2. Oktober 2008 Diese Dissertation ist auf den Internetseiten der Hochschulbibliothek online verfügbar. The work presented in this thesis was carried out at the Institut für Organische Chemie der RWTH Aachen under the supervision of Professor Dr. Hans-Joachim Gais from September 2004 to March 2008. First of all, I would like to thank Professor Dr. Gais for giving me the opportunity to carry out my PhD in his research group, for his excellent supervision and useful discussions. I would like to thank Professor Dr. Dieter Enders and Professor Dr. Albrecht Salzer for their contribution as examiners. Furthemore I would like to thank Cornelia Vermeeren for HPLC and GC analyses, as well as her involvement in the group.