Synthesis, characterization and chemical modification of a novel cationic polyelectrolyte poly(methylene amine) [Elektronische Ressource] / Nihar Ranjan Kundu

Synthesis, characterization and chemical modification of a novel cationic polyelectrolyte poly(methylene amine) Dissertation Zur Erlangung des Grades “Doktor der Naturwissenschaften” am Fachbereich Chemie, Pharmazie und Geowissenschaften der Johannes Gutenberg-Universität Nihar Ranjan Kundu Geboren in Jajpur / India Mainz, 2007 Dedicated to my parents JJJJaaaaiiii MMMMaaaattttaaaa DDDDiiii Perseverance pays and pays substantially…. TABLE OF CONTENTS CHAPTER 1: GENERAL INTRODUCTION 1.1 A brief introduction to commercially available aliphatic polyamine s 1 1.1.1 Branched poly(ethyleneimine) 1 1.1.2 Synthetic scheme for linear poly(ethyleneimine) 2 1.2 Polyallylamines. 3 1.2.1 Synthetic scheme for poly (Diallyldimethylammoniumchloride)(PDADMAC) 3 1.3 Polyvinylamine 4 1.3.1 Synthetic scheme for polyvinylamine 5 1.4 Applications of polyamines and their hydrochlorides 5 1.4.1 Paper manufacturing 6 1.4.2 Mining industry 7 1.4.3 Water treatment industry 7 1.5 Derivatization of amines 11 1.5.1 Photosensitive polymers 10 1.5.2 Brush polymers 12 1.5.3 Polyampholytes 14 1.