Surface selective and controllable photo-grafting for synthesis of tailored macroporous membrane adsorbers [Elektronische Ressource] = Oberflächenselektive und kontrollierbare Photopfropfung für die Synthese von maßeschneiderten makroporösen Membranadsorbern / by Dongming He

Surface-selective and Controllable Photo-grafting for Synthesis of Tailored Macroporous Membrane Adsorbers (OberflächenselektiveundkontrollierbarePhotopfropfungfürdieSynthesevonmaßgeschneidertenmakroporösenMembranadsorbern)byDongmingHeJiangxi, China ThesissubmittedtotheDepartmentofChemistryofUniversitätDuisburg&Essen,inpartialfulfillmentof therequirementsofthedegreeofDr.rer.nat.ApprovedbytheexaminingcommitteeonJuly 3, 2008:Chair :Prof.Dr.HeinzWilhelmSieslerAdvisor :Prof.Dr.MathiasUlbrichtReviewer :Prof.Dr.ThomasSchrader Essen,2008 iAbstract Photo&grafting is a straightforward and promisingetchnique for surface modification ofpolymeric membranes. This work emphasized on the development and investigation ofsurface&selectivephoto&graftingmethodfrompolaorrganicsolution;ontheotherhand,onthepreparationofmembraneadsorbersviatheproposedgraftingmethodsandevaluationoftheresultingmembraneadsorbers.Two novel surface&selective photo&grafting methodshave been developed: synergistimmobilization and iniferter immobilization methods.